Ethylenediamine and piperazine sensitivity.

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Hyperfine Structure and Tunneling Motion in Ethylenediamine

The first investigation of the microwave spectrum of ethylenediamine (NH CH –CH NH ) showed that in the gas phase this molecule occurs in two conformers which both exhibit a large amplitude tunneling motion corresponding to an interchange of the roles of the amino groups. In conformer I, the tunneling splitting is about 172 MHz while it is only 2.7 MHz in conformer II. In the paper an analysis ...

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ژورنال

عنوان ژورنال: BMJ

سال: 1983

ISSN: 0959-8138,1468-5833

DOI: 10.1136/bmj.287.6390.463